There really is no planning involved... just follow the path for each character, and if you run out of orbs, just wait until you recieve some before continuing on....
As for simple boss kills... Use Yuna during normal battles, even if you find her useless. Making her stronger will make the Aeons' stronger. While doing that, max out all the limit breaks for all her Aeons', and don't use them. Save them for Boss battles. What you do is weaken the Boss as much as you can with normal attacks, and then bring Yuna out and use her Aeons' final attacks to finish them off. You'll only have one turn with each Aeon...because they'll be easily killed, so make that first turn there final attack. Only exception are bosses with 2 or more forms, in that case you save them for the final form... or split them up.
Also, Aeons' 9999 cap limits will unlock depending on the ultimate weapons you've found and unlocked... per character. Bahamut's 9999 cap limit is unlocked from the beginning, I think...
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