It will actually look better then on the 3DS. The reason being?
The current 3DS has two ways of playing DS games, native resolution and enlarged. The native resolution keeps the same resolution as they do on the DS, meaning DS games actually appear pretty small. The enlarged way is worse quality than if you were playing on a DS but of a very similar size screen, the reason for the quality drop is because the 3DS has a better resolution meaning to keep the same size it must spread it's pixels across a bigger resolution.
The reason DS games will look better on the 3DS XL is simple. The XL has the same resolution as the 3DS, meaning that playing DS games in their native resolution will appear about the same size as if you were playing them on DS because the XL has a same resolution but a bigger screen. If you were to play the DS games in the enlarged way (what I've called it) then there is possibility that they could look worse because as on the 3DS they are stretching out across a higher resolution AND on a bigger screen.
In conclusion: if you play DS games in their native resolution they will appear the same screen size as on the DS and exactly the same quality as if you were playing on DS.
I hope this makes sense to everyone.
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