well theres two ways. holding alt and pressing tab will usually do it. itll minimise the game and bring you back to the desktop. however some games can be stuborn and require one to holf down ctrl and alt and then press del (aka the three fingered salute). this will allow you to open task manager and can sometimes force a game to minimise. however this suggestion comes with a warning: games that dont respond to alt-tab probably dont like being minimised. so minimising a game with the three fingered salute may cause the game to crash when you try and maximise it.
Ever since I got a Logitech G11 keybaord, I've never been happier, controlling itunes with the music buttons on it. But year, either use steam ingame browser to run music, or use windowed mode. Another expensive option is dual monitors
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