I don't think there is a cheat for getting more caps, but...
try to stock up on as much ammo as possible, even for the guns you don't use. Ammo weighs nothing and you can find tons of it in some places to sell back for a decent amount.
Also, get with Walter in Megaton to fix the pipes so he'll buy scrap metal from you. There's tons of it out there, and he'll give you 10 caps for each piece.
Another guy you want to set a deal up with is Murphy at the Seneca station for Sugar Bombs. He'll give you 30 caps a box, and they're also pretty easy to find.
The name of the game is scavenge, scavenge, scavenge. If it has some value and you can carry it, take it.
You could also just go the evil route and kill shopkeepers to get some ammo :)
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