Just as a general rule, remember that Proteins, Irons, and those other drinks give 10 EVs for that stat; but it won't bring it any higher than 100, so use them first.
If you mess up, use the following berries until the EV for that stat is at zero in order to start again; Pomeg = HP, Kelpsy = Attack, Qualot = Defense, Hondew = Special Attack, Grepa = Special Defense, and Tamato = Speed. Remember when you said EV training your starter is impossible? With these, it's not only possible, but easy. They'll also make your Pokemon exceptionally happy in the process.
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