Yeah it should run... but you might want to upgrade your video card soon though... Vista is a system hog so most game wont run all that great with that video card of yours you have enough ram and you CPU is a little on the slow side but if you just gunna be running Sims2 then you should be fine... just dont expect amazing performance... if your planing to get Sims3 then this set up wont cut it.
Ill go for more ram and a 800watt PSU for Future Proofing... and i hope its 64 bit and not 32bit Vista you have listed there... as of now Intell is out performing AMD so you might want to rethink your choice of CPU... I'm not a fan of ATI Video Cards but eh what ever floats your boat.
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