Immortal or not, Goku would still beat him. Goku would just turn SSJ3, grab the Itachi, and take him into the Hyperbolic Time Chamber, destroy the exit/entrance, use Instant Transmission to teleport to a really far off place in the Hyperbolic Time Chamber while holding Itachi so it brings him too, teleport somewhere else, yell loud enough to rip open a dimensionsional rift, and escape through it. Now he doesn`t have to deal with Itachi. Instant Transmission, according to DBZ Buu`s Fury as stated by Goku himself, allows you to move at the speed of light.
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