Finishing the fight against Dagoth Ur, going out of the volcano and seeing blue skies above Red Mountain. - Morrowind
Pretty much whole last 20% of Fahrenheit/Indigo Prophecy.
Epilogue of The Witcher.
Knife fight against Krauser. - Resident Evil 4
Tyrant, second fight. Killing Alexander. - Resident Evil: Code Veronica X
Quiz. - Banjo Kazooie
Seeing torn up Washington Monument up-close. - Fallout 3
Sovereign going down. Conversation with Vigil. - Mass Effect - Definitely my favorite non-action gaming moment ever. Pretty much the whole awesome story is explained in 5 minute conversation with an AI. All questions that have bothered you for the last 10+ hours of the game are explained. The truth you found was disheartening but you had to break the cycle.
A trip to the country mission. Ending of the lucky bastard mission on the docks. Final fight. - Mafia
Too many missions to name them all in San Andreas.
Experiencing open-endedness of GTA 3.
Getting on the alien planet. - Half Life
Going back to your home. - Red Dead Redemption
Couple of moments in God of War 1 and 2.
Ending of Max Payne. Couple of missions in Max Payne 2.
The bank mission in Splinter Cell: Chaos Theory.
Final fight in Turok 2.
Much, much more to remember. I didn't go to detail because if you haven't played these games then it's not really worth it for me to give description because those moments must be experienced. Reading about them won't give you much insight and it would take too much of my time. The only exception is Mass Effect because I still fondly remember that moment of the best story out of all games that I have played.
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