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Depends how you rate a solo, blisteringly fast (Dragonforce, Ywingie Malmsteen, Metallica, etc etc) or just a memorable piece of music (Pink Floyd, Rush, Zeppelin,) Personally;
Comfortably Numb (Live on P.U.L.S.E) - Pink Floyd
Hotel California - The Eagles
Like a Hurricane - Neil Young
Sometimes I Feel Like Screaming - Deep Purple
Stairway to Heaven - Led Zeppelin
Romanticide - Nightwish
The Chain - Fleetwood Mac
And many more...
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