Civ V has 18 different nations (America, Arabia, Aztec, China, Egypt, England, France, Germany, Greece, India, Iroquois, Japan, Ottoman, Persia, Rome, Russia, Siam, and Songhai).
Notable absences to me are Spain, the Zulus, and Portugal. Babalonia is available through prepurchase and likely DLC
For anybody who doesn't know Songhai is what later became Mali and Ghana
Link:
http://www.gamespot.com/pc/strategy/civilizationv/news.html?sid=6272395&om_act=convert&om_clk=picks&tag=picks%3Btitle%3B4&mode=previews&page=2
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