Make sure that you've correctly followed the instructions that came with your particular headset. Regardless though, after you've paired it with your Playstation 3, under Accessory settings, make sure that you are "connected" and there is a blue dot next to your bluetooth device. Everytime I want to use my mic, I turn on the mics power button, then push the PS button once, and go to Accessory Settings -> Manage Bluetooth Devices, then hit triangle on my device, then hit connect. It should, and will work after that.
Some games have hotkeys, I'm not too sure for Killzone 2, as I've played it a lot online, I haven't used my mic for it. But I'm guessing the default setting, or only setting, is no hotkey, and you just speak, because I've seen a LOT of people who CONSTANTLY breathe into their mic, and not mute it. If you have the original Sony bluetooth headset (Which is the ONLY great headset) it has a Mute button. USE IT more often people. You cannot even imagine the amounts of breathing other people can hear, and you cannot.
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