The only thing I can think of that is hard at the beggining is getting mobbed by 3 or 4 enemies at once or running into random yao guai.
It is a must that your character has at least one combat skill at 35 - 40 right from the start of the game. Small guns is easily the best choice if you aren't gonna rely heavily on combat because small guns are very common, do a lot of damage, and you can use wide range of guns. Pistols, shotguns and SMG are great up close, assault rifles and rifles are good all around guns, and scoped revolver and sniper are only good guns in the game to use at long range ( apart from scoped Gauss gun ( energy weapon ) introduced in Operation Anchorage DLC ). Big Guns are close range, lots of ammo guns or explosive guns. Energy weapons are good too but I prefer Small guns. I also had boatloads of fun with melee, hand to hand and explosive weapons. If you are fast or well armored you can quickly aproach enemies and tear them to pieces with axes, power fists, rippers. Unique explosives like nuka grenade and bottlecap mine can do as much damage as more powerfull big guns. Grenades and mines are very common, grenades can sometimes be troublesome to throw accurately. Demolition expert, a perk available at lvl6 increases explosive damage by 20% each time you take it, up to 3 times, that can make your explosives very powerfull.
I suggest you to go to Springvale school, you can get some pistols there and assault rifle located in bug mine. From there go to Megaton, find Moira in her shop, she can give you good armor, you can do 1st chapter of her book without much problems. From there it's totally up to you where to go next. You can wander in the wastes north and west of Megaton or you can go visit more straightforward DC ruins. Wherever you go you gonna have lots of fun.
Another thing, if you have DLC I don't suggest doing them. You can try Anchorage from at least level 10, same goes for Pitt, Point Lookout has very strong enemies with very powerfull repeater rifles, it is however the most interesting of all DLCs. Wait until level 15 but you can try it out before that. I was about level 14 when I first went into there. I had very high small guns skill and was struggling to kill them with powerfull Double barreled shotgun. You can get into conflicts with larger number of enemies very easily, and the first quest in main quest of that DLC requires you to kill at least 50 of those enemies in a small mansion ( awesome quest by the way ).
Don't try to make pacifist character and you should be just fine. I don't recommend stealth character for your first playthrough but whatever suits you.
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