For starters, you need to figure if you have the right Q6600 for overclocking. Check the box for the PCG number if it is a 05B, then you have a "B3" stepping which is not your best choice for OC, but if you have a 05A, then you a a "G0" stepping which is better suited for OC.
One problem with overclocking is that you really need to know how to do it properly with your motherboard and CPU, so following a generic guide may not be the best idea. But you can search Google for forum topics on overclocking+Q6600+EVGA 780i and read through the descriptions.
In most cases, yes. If this system is an OEM system such as a DELL or HP, then the OS could be associated with the system's BIOS. But the only way to know for certain is to just try it. Try to install it and if it works, cheers!
If you know enough to bulld your own gaming rig, you should be smart enough to know how to find some older games that will run on his older PC. Start with those released in 1998 and work your way towards now...
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