To start, an i7 is usually considered overkill for gaming.
1. Since you only plan to play on 1 screen (I'm assuming it's 1080p since it's a TV) you will only need 1 card. The GTX 770 or GTX 970 is a good all around card price vs. performance. You could go for the 980 if you have the money, but that seems overkill for you IMO.
2. A good liquid cooling system will be quieter and possibly allow you to overclock further. It depends on the cooling system though.
3. A descent monitor will have better refresh rates and less input lag than most TVs. Your TV can certainly work fine for now though. You might not even notice a difference.
4 8GBs for now, 16GBs to "futureproof"
5. x99 is for a different set of CPUs (Haswell-E) and DDR4 RAM. It's brand new and costs quite a bit more for the motherboard, CPU, and RAM.
6. Essentially SLI and Crossfire (Xfire) are the terms used by Nvidia and AMD respectively for using more than one of the same graphics card in a system work together.
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